The MSWI ash that contains an outsized range of serious metal substances may be a subsidiary product of waste burning power generation technology. If the MSWI ash is disposed improperly, serious metal pollutants can cause a good threat to environmental safety and human health. Supported the technology of electrokinetic remedy, the practicability of removing serious metal pollutants from the MSWI ash employing a changed electrokinetic remedy device - cylinder device was evaluated during this study. Differing from the standard cuboid device with the amount quantitative relation of the cathode chamber to the anode chamber being, the amount quantitative relation of the cathode chamber to the anode chamber of the cylinder device. Changes in parameters, like hydrogen ion concentration values and conduction within the cathode and also the anode chambers further as current and voltage within the sample space were analyzed below the voltage gradient of 2V. once the experiment, the typical removal efficiencies. It indicates that the cylinder device is effective in removing serious metals from the MSWI ash. Adopting the cylinder device for the experimental study on the electrokinetic remedy technology may give a far better method of thinking for the longer term engineering practices and applications [1-3].